1. Bring 1 1/2 cups water to a boil in a medium saucepan. Add barley and simmer covered for 35-40 minutes or until just tender. Drain and set aside. 2. Preheat oven to 400F. 3. Heat oil in frying pan over medium heat. Add onion and cook for 5 minutes, then add garlic, and remaining vegetables and chiles and cook for another 5 minutes. 4. Add the barley to the frying pan and toss with the vegetable mixture. Cook for 5 minutes, stirring occasionally. Transfer to a bowl and let cool. 5. In a large bowl, whisk the egg whites until soft peaks form - the mixture should be stiff, but not dry. Stir a third of the egg whites into the cooled barley mixture. Then fold in the remaining whites. Fold in the goat cheese. Season with black pepper. Spoon the mixture into a buttered shallow ovenproof dish. Bake until golden (about 20 minutes).